Consider the following statements regarding depletion of the ozone layer: 1. Excessive release of chlorine and bromine in the environment from man-made compounds, such as chlorofluorocarbons. 2. Occurrence of certain natural phenomena such as sunspots, and stratospheric winds. 3. Degradation of materials by ultra-violet radiation 4. Major volcanic eruptions. Which of the above can be categorized as causing ozone depletion?
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